综合文献

Metal–organic framework materials for production and distribution of ammonia

发布日期
作者
Xue Han; Sihai Yang; Martin Schröder

摘要

Abstract Click to copy section link Section link copied! High Resolution Image Download MS PowerPoint Slide The efficient production of ammonia (NH 3 ) from dinitrogen (N 2 ) and water (H 2 O) using renewable energy is an important step on the roadmap to the ammonia economy. The productivity of this conversion hinges on the design and development of new active catalysts. In the wide scope of materials that have been examined as catalysts for the photo- and electro-driven reduction of N 2 to NH 3 , functional metal–organic framework (MOF) catalysts exhibit unique properties and appealing features. By elucidating their structural and spectroscopic properties and linking this to the observed activity of MOF-based catalysts, valuable information can be gathered to inspire new generations of advanced catalysts to produce green NH 3 . NH 3 is also a surrogate for the hydrogen (H 2 ) economy, and the potential application of MOFs for the practical and effective capture, safe storage, and transport of NH 3 is also discussed. This Perspective analyzes the contribution that MOFs can make toward the ammonia economy. This publication is licensed under CC-BY 4.0 . License Summary* You are free to share (copy and redistribute) this

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within the parameters below: Creative Commons (CC): This is a Creative Commons license. Attribution (BY): Credit must be given to the creator. View full license *Disclaimer This summary highlights only some of the key features and terms of the

actual license. It is not a license and has no legal value. Carefully

review the actual license before using these materials. License Summary* You are free to share (copy and redistribute)

this article in any medium or format and to adapt (remix, transform, and build upon) the material for any

purpose, even commercially within the parameters below: Creative Commons (CC): This is a Creative Commons

license. Attribution (BY): Credit must be given to the creator. View

full license *Disclaimer This summary highlights only some of the key features and terms of

the

actual license. It is not a license and has no legal value.

Carefully

review the actual license before using these materials. License Summary* You are free to share (copy and redistribute)

this article in any medium or format and to adapt (remix, transform, and build upon) the material for any

purpose, even commercially within the parameters below: Creative Commons (CC): This is a Creative Commons

license. Attribution (BY): Credit must be given to the creator. View

full license *Disclaimer This summary highlights only some of the key features and terms of

the

actual license. It is not a license and has no legal value.

Carefully

review the actual license before using these materials. ACS Publications Copyright © 2023 The Authors. Published by American Chemical Society Subjects what are subjects Article subjects are automatically applied from the ACS Subject Taxonomy and describe the scientific concepts and themes of the article. Catalysts Composites Materials Metal organic frameworks Metals

原文链接

DOI: 10.1021/jacs.2c06216