化学合成；材料科学。
化学合成；材料科学；有机合成中间体；有机发光材料中间体；空穴传输材料
合成路线 1（1. 合成：105946-82-5）
产率：93%
合成条件：at 65 - 90℃; for 6.50 h; Inert atmosphere
实验步骤：在氩气氛下，称取4-溴 - 联苯47.0g（201.6mmol），碘23. 0g（90.6mmol），高碘酸氢二钠9. 4g（41.2mmol），加水42ml，360ml乙酸 ，11毫升硫酸，65℃，搅拌30分钟，至90℃再搅拌6小时。反应后，将反应混合物注入冰水中，过滤。 用水洗涤后，再用甲醇洗涤，得到67.0g白色固体（收率93％）。
参考文献：
- [1] Patent: CN105431417, 2016, A. Location in patent: Paragraph 0214; 0215; 0216; 0217 [2] Patent: US2011/95269, 2011, A1 [3] Patent: US2012/65432, 2012, A1. Location in patent: Page/Page column 47 [4] Synthesis, 2002, # 9, p. 1201 - 1212 [5] Journal of the American Chemical Society, 2016, vol. 138, # 50, p. 16337 - 16344 [6] Tetrahedron, 2006, vol. 62, # 52, p. 12408 - 12414 [7] Justus Liebigs Annalen der Chemie, 1960, vol. 634, p. 84 - 104 [8] Patent: US2007/179318, 2007, A1. Location in patent: Page/Page column 14 [9] Patent: US2008/108832, 2008, A1. Location in patent: Page/Page column 50 [10] Patent: EP2177516, 2010, A1. Location in patent: Page/Page column 46 [11] Patent: US2007/167654, 2007, A1. Location in patent: Page/Page column 19 [12] Patent: EP2295421, 2011, A1. Location in patent: Page/Page column 48 [13] Patent: EP2348017, 2011, A1. Location in patent: Page/Page column 47 [14] Patent: EP2364980, 2011, A1. Location in patent: Page/Page column 71; 90 [15] Patent: EP2364980, 2011, A1. Location in patent: Page/Page column 90 [16] Patent: EP2399906, 2011, A1. Location in patent: Page/Page column 25; 37 [17] Patent: EP2415752, 2012, A1. Location in patent: Page/Page column 31 [18] Patent: EP2468725, 2012, A1. Location in patent: Page/Page column 118-119 [19] Patent: EP2484665, 2012, A1. Location in patent: Page/Page column 62 [20] Patent: EP2527334, 2012, A1. Location in patent: Page/Page column 87 [21] Patent: EP2589596, 2013, A1. Location in patent: Paragraph 0109 [22] Patent: KR101551591, 2015, B1. Location in patent: Paragraph 0312-0313
