作为有机电子材料(如聚合物太阳能电池、有机场效应晶体管等)的关键中间体或功能单体,用于制备高性能共轭聚合物材料,在有机电子器件中发挥重要作用。
有机电子材料; 高分子材料
合成路线 1(1. 合成:1160823-77-7)
产率:87%
合成条件:Stage #1: With sodium hydroxide; zinc In water at 120℃; for 13 h; Stage #2: With tetrabutylammomium bromide In water
实验步骤:称取2.2g苯并[1,2-b:4,5-b']二噻吩-4,8-二酮,加入1.5g单一添加锌粉,6g氢氧化钠,蒸馏水35g,加热回流, 油浴温度控制在120℃,反应时间:13h;溶液迅速从黄色变为红色。随着反应的进行,溶液均匀。此时,5.8g的C8H17Br和0.11g的催化剂当量为 加入四丁基溴化铵TBAB,随着反应的进行,溶液由黑色变为红色,最终变为淡黄色。终止反应:加水淬灭。反应过程:用乙醚多次萃取,无水MgSO4干燥,旋转溶剂,真空 干燥至恒重,得到产物4,8-双(2-乙基 - 己氧基)苯并[1,2-b:4,5-b'二噻吩3.9g,产率为87%。
参考文献:
- [1] Chemistry - A European Journal, 2015, vol. 21, # 45, p. 16252 - 16265 [2] Patent: CN105968125, 2016, A. Location in patent: Paragraph 0094; 0095; 0096; 0097; 0152; 0153 [3] Patent: CN105968124, 2016, A. Location in patent: Paragraph 0095; 0096; 0097; 0098 [4] Polymer, 2010, vol. 51, # 13, p. 2897 - 2902 [5] RSC Advances, 2014, vol. 4, # 49, p. 25532 - 25539 [6] Journal of the American Chemical Society, 2014, vol. 136, # 27, p. 9608 - 9618 [7] Journal of Polymer Science, Part A: Polymer Chemistry, 2010, vol. 48, # 8, p. 1822 - 1829 [8] Reactive and Functional Polymers, 2012, vol. 72, # 11, p. 897 - 903 [9] Organic Electronics: physics, materials, applications, 2016, vol. 37, p. 312 - 325 [10] Patent: KR2015/48636, 2015, A. Location in patent: Paragraph 0477-0479 [11] Patent: KR2015/114418, 2015, A. Location in patent: Paragraph 0475-0478 [12] Polymer, 2011, vol. 52, # 2, p. 415 - 421 [13] Journal of Polymer Science, Part A: Polymer Chemistry, 2011, vol. 49, # 16, p. 3604 - 3614 [14] Australian Journal of Chemistry, 2014, vol. 67, # 5, p. 711 - 721 [15] Macromolecules, 2011, vol. 44, # 6, p. 1414 - 1420 [16] Chemistry of Materials, 2010, vol. 22, # 9, p. 2696 - 2698 [17] Macromolecules, 2011, vol. 44, # 17, p. 6659 - 6662 [18] Macromolecules, 2012, vol. 45, # 3, p. 1710 - 1714 [19] Macromolecules, 2012, vol. 45, # 3, p. 1208 - 1216 [20] Journal of Polymer Science, Part A: Polymer Chemistry, 2014, vol. 52, # 7, p. 1028 - 1036 [21] Journal of Nanoscience and Nanotechnology, 2014, vol. 14, # 8, p. 6038 - 6042 [22] Patent: US8933441, 2015, B2. Location in patent: Page/Page column 45 [23] Chemical Physics Letters, 2017, vol. 667, p. 254 - 259 [24] Physical Chemistry Chemical Physics, 2017, vol. 19, # 31, p. 20513 - 20522 [25] Patent: KR2018/38433, 2018, A. Location in patent: Paragraph 0215-0219