化学合成。
化学合成; 医药; 光电材料
合成路线 1（1. 合成：28320-32-3）
产率：99%
合成条件：With tetrabutylammomium bromide; sodium hydroxide In dimethyl sulfoxide for 5 h; Sonication
实验步骤：（1）2,7-二溴芴（9.72克，30毫摩尔），四正丁基溴化铵（0.08克，0.25毫摩尔），甲基碘（12.8克，90毫摩尔）NaOH溶液10毫升，DMSO 120毫升，加入250毫升单 - 烧瓶，超声波反应5h（100W），反应后倒入500mL水中，抽滤30min后，用水洗涤，干燥，得到淡黄色固体10.5g，收率99％。
参考文献：
- [1] Patent: CN106349163, 2017, A. Location in patent: Paragraph 0080; 0081; 0099; 0100; 0113; 0114 [2] Patent: CN108409668, 2018, A. Location in patent: Paragraph 0075-0076; 0078 [3] Patent: EP1860097, 2007, A1. Location in patent: Page/Page column 21; 22 [4] Patent: US8058450, 2011, B2. Location in patent: Page/Page column 43 [5] Journal of Organic Chemistry, 2004, vol. 69, # 3, p. 987 - 990 [6] Journal of the American Chemical Society, 2013, vol. 135, # 16, p. 6184 - 6191 [7] Journal of the American Chemical Society, 2017, vol. 139, # 5, p. 2118 - 2118 [8] Patent: EP1762553, 2007, A1. Location in patent: Page/Page column 27 [9] Dyes and Pigments, 2013, vol. 96, # 3, p. 705 - 713 [10] Organic and Biomolecular Chemistry, 2018, vol. 16, # 22, p. 4071 - 4075 [11] Angewandte Chemie, International Edition, 2015, vol. 54, # 19, p. 5641 - 5645 [12] Angewandte Chemie, 2015, vol. 127, # 19, p. 5733 - 5737,5 [13] Advanced Functional Materials, 2013, vol. 23, # 10, p. 1323 - 1330 [14] Tetrahedron Letters, 2016, vol. 57, # 45, p. 4978 - 4982 [15] Luminescence, 2015, vol. 30, # 5, p. 549 - 555 [16] Journal of Organic Chemistry, 2015, vol. 80, # 23, p. 11818 - 11848 [17] Journal of the American Chemical Society, 2003, vol. 125, # 26, p. 7796 - 7797 [18] Patent: WO2010/50781, 2010, A1. Location in patent: Page/Page column 141 [19] Patent: US2011/54229, 2011, A1. Location in patent: Page/Page column 20 [20] Patent: US2011/152587, 2011, A1. Location in patent: Page/Page column 22; 24 [21] Tetrahedron, 2014, vol. 70, # 41, p. 7551 - 7559 [22] Journal of Materials Chemistry C, 2015, vol. 3, # 6, p. 1208 - 1224 [23] Chemical Communications, 2015, vol. 51, # 56, p. 11276 - 11279
