873-94-9 3,3,5-三甲基环己酮

运输信息：常温运输。危险描述：非危险化学品，WGK Germany:1，RTECS号:GW2185000，TSCA listed，海关编码:29142200，存储类别:10 - 可燃性液体，危险性类别:眼部刺激 类别2，特异性靶器官毒性-一次接触，类别3

用作硝酸纤维素、低分子量聚氯乙烯以及醇酸树脂的优良溶剂

化学合成

合成路线 1（1. 合成：873-94-9）

• 步骤: 在氢气氛下将0.015g催化剂和2mmol反应物加入10mL乙醇中，通过薄层色谱（TLC）监测反应，原料完全消失后过滤分离催化剂，减压除去溶剂得到纯产物。
• 条件: With hydrogen In ethanol at 20℃; for 2.50 h
• 产率: 94%
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合成路线 2（2. 合成：873-94-9）

• 步骤: 首先将GO（0.01g）加入水（3mL）中，超声波处理产生稳定胶体悬浮液；加入醇（2mmol）和(NH₄)₅H₅[H₂(WO₄)₆]（0.03mmol，M=1602），室温搅拌15分钟；逐滴加入过氧化氢（30wt%，8mmol）并加热至70℃直至反应完全（TLC监测）；反应完成后离心分离GO，加入乙酸乙酯萃取有机成分，减压浓缩有机萃取物，柱色谱纯化。
• 条件: Stage #1: With ammonium tungstate In water at 20℃; for 0.25 h; Green chemistry；Stage #2: With dihydrogen peroxide In water at 70℃; for 11 h; Green chemistry
• 产率: 90%
• 参考文献: [1] Synlett, 2018, vol. 29, # 4, p. 447 - 451；[2] Bulletin of the Chemical Society of Japan, 1986, vol. 59, p. 3297 - 3298；[3] Journal of the American Chemical Society, 1945, vol. 67, p. 1432,1434；[4] Journal of the American Chemical Society, 1945, vol. 67, p. 1432,1434

通用方法（异佛尔酮氢化）

• 步骤: 在标准氢化反应条件下，将0.015g催化剂与2mmol异佛尔酮溶于10mL乙醇中，TLC监测反应，异佛尔酮完全转化后过滤移除催化剂，减压蒸除溶剂得纯净产物。
• 条件: 氢化反应条件（具体条件未详述）
• 产率: 未明确（原始数据未提供）
• 参考文献: [1] Tetrahedron, 1994, vol. 50, # 4, p. 973 - 978；[2] Chemical Communications, 2005, # 25, p. 3207 - 3209；[3] Green Chemistry, 2011, vol. 13, # 5, p. 1133 - 1137；[4] RSC Advances, 2013, vol. 3, # 36, p. 15608 - 15612